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Luminescent Er(Ⅲ)-Chelated Dendritic Complexes Having Light-Harvesting Effect and Their Synthetic Me 发明申请

2022-07-31 1960 1073K 0

专利信息

申请日期 2024-11-17 申请号 KR1020030102338
公开(公告)号 KR1020040090385A 公开(公告)日 2004-10-22
公开国别 KR 申请人省市代码 全国
申请人 KIM HWAN KYU
简介 PURPOSE : A novel dendrimer type organic light emitting complex comprising a rare earth metal element is provided to give a light harvesting effect by means of molecular engineering, to improve solubility to a polymer medium, and to prevent coagulation of the rare earth metal element. CONSTITUTION : The dendrimer type organic light emitting complex comprising a rare earth metal element has a structure represented by formula 1, wherein Ln is Er; a is 0, 1 or 2; B is a compound selected from compounds represented by formula 2 or the like. The method for preparing the dendrimer type organic light emitting complex comprises : adding a component selected from KH, B-CO2H, terpyridine or bipyridine into a vacuum dried flask under nitrogen stream; dissolving the mixture with an organic solvent; stirring the mixture till hydrogen gas is not generated therefrom, adding thereto a solution of anhydrous ErCl3 and methanol and stirring it for one day; removing and drying the solvent from the solution in vacuum condition, washing the resulted product with diethylether for several times, and then vacuum drying the resulted compound. © KIPO 2005


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